Starc was left out of the first Test at Edgbaston but Australia will give him the nod as the third quick at the toss on Wednesday morning.
The Lord's pitch has a notable green tinge prompting England to leave out a frontline spinner with the ball expected to seam around.
There was a light drizzle around London on Wednesday morning, but no significant rain is forecast for day one.
Starc's recall comes after England made a point to go after Boland at Edgbaston, with the Victorian seamer conceding more than five runs an over in both innings.
Starc was also expensive in the World Test Championship final against India that preceded the Ashes, but Australia rate his attacking wicket-taking ability.
AUSTRALIA: David Warner, Usman Khawaja, Marnus Labuschagne, Steve Smith, Travis Head, Cameron Green, Alex Carey, Pat Cummins (capt), Scott Boland, Nathan Lyon, Josh Hazlewood.
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